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    CAS 115-37-7

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    CAS 115-37-7
    Also known as: Paramorphine, 115-37-7, Thebain, 3-o-methyl-oripavin, 4,5alpha-epoxy-3,6-dimethoxy-17-methyl-6,8-morphinadien, Einecs 204-084-1
    Molecular Formula
    C19H21NO3
    Molecular Weight
    311.4  g/mol
    InChI Key
    FQXXSQDCDRQNQE-VMDGZTHMSA-N
    FDA UNII
    2P9MKG8GX7
    A drug that is derived from opium, which contains from 0.3-1.5% thebaine depending on its origin. It produces strychnine-like convulsions rather than narcosis. It may be habit-forming and is a controlled substance (opiate) listed in the U.S. Code of Federal Regulations, Title 21 Part 1308.12 (1985). (From Merck Index, 11th ed)
    1 2D Structure

    CAS 115-37-7

    2 Identification
    2.1 Computed Descriptors
    2.1.1 IUPAC Name
    (4R,7aR,12bS)-7,9-dimethoxy-3-methyl-2,4,7a,13-tetrahydro-1H-4,12-methanobenzofuro[3,2-e]isoquinoline
    2.1.2 InChI
    InChI=1S/C19H21NO3/c1-20-9-8-19-12-5-7-15(22-3)18(19)23-17-14(21-2)6-4-11(16(17)19)10-13(12)20/h4-7,13,18H,8-10H2,1-3H3/t13-,18+,19+/m1/s1
    2.1.3 InChI Key
    FQXXSQDCDRQNQE-VMDGZTHMSA-N
    2.1.4 Canonical SMILES
    CN1CCC23C4C(=CC=C2C1CC5=C3C(=C(C=C5)OC)O4)OC
    2.1.5 Isomeric SMILES
    CN1CC[C@]23[C@@H]4C(=CC=C2[C@H]1CC5=C3C(=C(C=C5)OC)O4)OC
    2.2 Other Identifiers
    2.2.1 UNII
    2P9MKG8GX7
    2.3 Synonyms
    2.3.1 Depositor-Supplied Synonyms

    1. Paramorphine

    2. 115-37-7

    3. Thebain

    4. 3-o-methyl-oripavin

    5. 4,5alpha-epoxy-3,6-dimethoxy-17-methyl-6,8-morphinadien

    6. Einecs 204-084-1

    7. Unii-2p9mkg8gx7

    8. 2p9mkg8gx7

    9. (5r,9r,13s)-4,5-epoxy-3,6-dimethoxy-9alpha-methyl-6,8-morphinadien

    10. Chebi:9519

    11. Dea No. 9333

    12. Dtxsid7046099

    13. (4r,7ar,12bs)-7,9-dimethoxy-3-methyl-2,4,7a,13-tetrahydro-1h-4,12-methanobenzofuro[3,2-e]isoquinoline

    14. Ncgc00160239-01

    15. Thebaine [controlled Substance]

    16. Dtxcid5026099

    17. (5alpha)-6,7,8,14-tetradehydro-4,5-epoxy-3,6-dimethoxy-17-methylmorphinan

    18. 3,6-dimethoxy-17-methyl-6,7,8,14-tetradehydro-4,5alpha-epoxymorphinan

    19. Morphinan, 6,7,8,14-tetradehydro-4,5-alpha-epoxy-3,6-dimethoxy-17-methyl-

    20. Cas-115-37-7

    21. Tebaine

    22. Thenaine

    23. Kodein

    24. Thebaine, Powder

    25. Ncgc00247709-01

    26. Thebaine [mi]

    27. D0o2ld

    28. Thebaine [who-dd]

    29. Schembl37580

    30. Chembl403893

    31. Ids-nt-002

    32. Schembl19880976

    33. Thebaine 0.1 Mg/ml In Methanol

    34. Fqxxsqdcdrqnqe-vmdgzthmsa-n

    35. Bdbm224032

    36. Tox21_111751

    37. Tox21_112863

    38. Ls-92171

    39. C06173

    40. Codeine Monohydrate Impurity G [ep Impurity]

    41. Q63392872

    42. Oxycodone Hydrochloride Impurity F [ep Impurity]

    43. Thebaine, European Pharmacopoeia (ep) Reference Standard

    44. Codeine Hydrochloride Dihydrate Impurity G [ep Impurity]

    45. Codeine Phosphate Hemihydrate Impurity G [ep Impurity]

    46. Codeine Phosphate Sesquihydrate Impurity G [ep Impurity]

    47. 6,7,8,14-tetradehydro-4,5-epoxy-3,6-dimethoxy-17-methylmorphinan

    48. Hydrocodone Hydrogen Tartrate 2.5-hydrate Impurity I [ep Impurity]

    49. (5-alpha)-6,7,8,14-tetradehydro-4,5-epoxy-3,6-dimethoxy-17-methylmorphinan

    50. (5.alpha.)-6,7,8,14-tetradehydro-4,5-epoxy-3,6-dimethoxy-17-methylmorphinan

    51. Morphinan, 6,7,8,14-tetradehydro-4,5-epoxy-3,6-dimethoxy-17-methyl-, (5alpha)-

    52. Morphinan, 6,7,8,14-tetradehydro-4,5-epoxy-3,6-dimethoxy-17-methyl-,(5.alpha.)-

    53. D4r

    2.4 Create Date
    2004-09-16
    3 Chemical and Physical Properties
    Molecular Weight 311.4 g/mol
    Molecular Formula C19H21NO3
    XLogP32.2
    Hydrogen Bond Donor Count0
    Hydrogen Bond Acceptor Count4
    Rotatable Bond Count2
    Exact Mass g/mol
    Monoisotopic Mass g/mol
    Topological Polar Surface Area30.9
    Heavy Atom Count23
    Formal Charge0
    Complexity585
    Isotope Atom Count0
    Defined Atom Stereocenter Count3
    Undefined Atom Stereocenter Count0
    Defined Bond Stereocenter Count0
    Undefined Bond Stereocenter Count0
    Covalently Bonded Unit Count1
    4 Pharmacology and Biochemistry
    4.1 MeSH Pharmacological Classification

    Convulsants

    Substances that act in the brain stem or spinal cord to produce tonic or clonic convulsions, often by removing normal inhibitory tone. They were formerly used to stimulate respiration or as antidotes to barbiturate overdose. They are now most commonly used as experimental tools. (See all compounds classified as Convulsants.)

    Narcotics

    Agents that induce NARCOSIS. Narcotics include agents that cause somnolence or induced sleep (STUPOR); natural or synthetic derivatives of OPIUM or MORPHINE or any substance that has such effects. They are potent inducers of ANALGESIA and OPIOID-RELATED DISORDERS. (See all compounds classified as Narcotics.)

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    7051-34-5
    Buprenorphine
    Integrated solutions for all your projects.
    M2i Group provides integrated solutions for all your p...
    Integrated solutions for all your projects.
    M2i Group provides integrated solutions for all your projects. We offer our clients an integrated partner, from early development to commercial supply of high-value niche fine chemicals for the pharmaceutical and biocontrol industry. Our offerings include:
    - Proprietary molecule portfolio: API, synthesis intermediates, key building blocks & pheromones
    - Custom development & manufacturing: Process development, industrialization & production
    - Contract Research: Outsourced research services
    - Consulting/accompaniment: R&D, innovation, key sourcing & industrial strategy
    m2i group Custom Synthesis

    Vietnam Medi Pharm 2024

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    Noramco

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    Noroxymorphone

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    33522-95-1
    Naloxone Hydrochloride
    Founded in 1979, Noramco specializes in the development and manufacturing of APIs for both opioid and non...
    Founded in 1979, Noramco specializes in the development and manufacturing of APIs for both opioid and non-opioid products. With expertise in controlled substance development and manufacturing, Noramco offers services like supply-chain integration for high-purity controlled substances, efficient routes to APIs, analytical data, stability studies, regulatory help, formulation-friendly particle size grades, extended technical packages, DEA-compliant security and production capacity from kilos to multi-ton supply. Noramco also offers world-class supply security for controlled substances, from Schedule I to Schedule III.
    Noramco

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    Noramco

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    Virtual BoothNoramco is a partner to the pharmaceutical industry for controlled substance development & manufacturing.
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    Noroxymorphone

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    33522-95-1
    Naltrexone
    Founded in 1979, Noramco specializes in the development and manufacturing of APIs for both opioid and non...
    Founded in 1979, Noramco specializes in the development and manufacturing of APIs for both opioid and non-opioid products. With expertise in controlled substance development and manufacturing, Noramco offers services like supply-chain integration for high-purity controlled substances, efficient routes to APIs, analytical data, stability studies, regulatory help, formulation-friendly particle size grades, extended technical packages, DEA-compliant security and production capacity from kilos to multi-ton supply. Noramco also offers world-class supply security for controlled substances, from Schedule I to Schedule III.
    Noramco

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    Parand Darou Pharma

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      Virtual BoothParand Darou is a knowledge-based company, focused on the production of Narcotic APIs.
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      3-O-Methyl Norbuprenorphine

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      16614-59-8
      Buprenorphine
      Parand Daro Pharmaceutical Company is a knowledge-based company that commenced operations in 2015, focusi...
      Parand Daro Pharmaceutical Company is a knowledge-based company that commenced operations in 2015, focusing on the production of narcotic medicinal substances. Parand Daro holds the distinction of being the second private sector company in Iran to obtain a license from the Food and Drug Organization to manufacture narcotic products. Leveraging opioid raw materials, Parand Daro has successfully produced potent medicinal substances, including codeine phosphate, noscapine, thebaine, papaverine and oxycodone. Apart from catering to domestic demand, Parand Daro has also expanded its reach by exporting its products to global markets.
      Parand Darou Pharma

      CPhI Worldwide, Milan

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      Parand Darou Pharma

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        Virtual BoothParand Darou is a knowledge-based company, focused on the production of Narcotic APIs.
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        Norbuprenorphine

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        78715-23-8
        Buprenorphine
        Parand Daro Pharmaceutical Company is a knowledge-based company that commenced operations in 2015, focusi...
        Parand Daro Pharmaceutical Company is a knowledge-based company that commenced operations in 2015, focusing on the production of narcotic medicinal substances. Parand Daro holds the distinction of being the second private sector company in Iran to obtain a license from the Food and Drug Organization to manufacture narcotic products. Leveraging opioid raw materials, Parand Daro has successfully produced potent medicinal substances, including codeine phosphate, noscapine, thebaine, papaverine and oxycodone. Apart from catering to domestic demand, Parand Daro has also expanded its reach by exporting its products to global markets.
        Parand Darou Pharma

        CPhI Worldwide, Milan

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        Atom Pharma

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          CYCLOPROPYL METHANOL

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          2516-33-8
          Naltrexone
          Atom pharma is ISO 9001:2015 integrated, fastest growing and reputed Pharmaceutical bulk drugs [API] and ...
          Atom pharma is ISO 9001:2015 integrated, fastest growing and reputed Pharmaceutical bulk drugs [API] and pharmaceutical Intermediates exporting company. We have the industry’s broadest portfolio of more than 80 high-quality API (active pharmaceutical ingredient) products, and more than 50 pharmaceutical intermediate. We offer the best APIs to our customers and have satisfied customers in over 20 countries. We ensure that our partners have the approved EUGMP, cGMP, USFDA, GMP, Halal-Kosher, and Korea FDA along with the documentation and systems that are required for a regulated market.
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          Chr. Olesen Synthesis A.S

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          Buprenorphine intermediate

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          Buprenorphine
          Chr. Olesen Synthesis is a Danish manufacturer of APIs and advanced intermediates. Chr. Olesen Synthesis ...
          Chr. Olesen Synthesis is a Danish manufacturer of APIs and advanced intermediates. Chr. Olesen Synthesis was established in 2012 after the Chr. Olesen Group acquisition of the multi-purpose synthetic production facility just south of Copenhagen. Chr. Olesen Synthesis is initially active with API’s comprising of molecules like Hydromorphone, Codeine Phosphate, Pramipexole, Terbinafine Risedronate, Tolfenamic Acid, Amphetamine derivatives and advanced intermediates for Buprenorphine and Tamsulosin.
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          Delta Finochem P Ltd

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          Cyclobutanecarboxylic acid

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          3721-95-7
          Naltrexone
          Delta Finochem Pvt Ltd. is a privately owned and professionally managed company, accredited by WHO-GMP & ...
          Delta Finochem Pvt Ltd. is a privately owned and professionally managed company, accredited by WHO-GMP & ISO 9001:2015 (Year of establishment 1994) Delta Finochem is a leading manufacturers of Active Pharmaceutical Ingredients (Generics), Drug Intermediates, Quaternary Ammonium Compounds, Quaternary Phosphonium compounds. Our focus is on niche products, with a presence in several countries. Our partners are essentially innovators and generic drug companies across the globe for whom we develop a range of new niche products.
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          Innovassynth Technologies (I) Ltd

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            Cyclopropyl Methyl Bromide

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            7051-34-5
            Buprenorphine
            Innovassynth Technologies (I) Ltd. formerly known as Chemicals Division of Indian Organic Chemicals Ltd. ...
            Innovassynth Technologies (I) Ltd. formerly known as Chemicals Division of Indian Organic Chemicals Ltd. came in to existence since 1st August 2002. It is a part of the well-known business group involved in activities like polyester fiber, polymers, pre-forms, and computer software among others. The company is catering to the needs of customers in the area of 'knowledge based R & D services' for the last 5 years, which include: Contract R & D, Custom Synthesis and Contract Manufacture In a very short period the company has established its name as a reliable partner in above area of activities and has joined hands with many prestigious companies in the field. The company has identified NUCLEOSIDES as a niche area and earned reputation as a supplier of various protected Nucleosides and a partner for Process research. The company is involved in business with well-known companies in various fields like pharmaceuticals, perfumes, agro chemicals, and fine and specialty chemicals. With two sites at its disposal, one already active at Khopoli near Mumbai and the other in the development stage at Chennai. It has already set up a cGMP Pilot Plant Facility where 10-15 Kg batch size is possible. It is going for US FDA approval in near future.
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            Inventys

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              Cyclopropane Carboxylic Acid

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              1759-53-1
              Buprenorphine
              INVENTYS Research Company – India’s Leading CDMO of Actives, Advanced Intermediates, and Specialty Ch...
              INVENTYS Research Company – India’s Leading CDMO of Actives, Advanced Intermediates, and Specialty Chemicals. A research-driven Exclusive Synthesis and CDMO company from India – with an established track record of demonstrated excellence in process development, process scale-up, process engineering, project management, and finally in consistent reliable custom manufacturing of chemicals for Crop Protection, Pharmaceutical, and other Fine / Specialty applications. INVENTYS advanced technologies ensure innovative, cost-effective, and safe processes.
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              Inventys

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                Cyclopropane Carboxylic Acid

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                1759-53-1
                Naltrexone
                INVENTYS Research Company – India’s Leading CDMO of Actives, Advanced Intermediates, and Specialty Ch...
                INVENTYS Research Company – India’s Leading CDMO of Actives, Advanced Intermediates, and Specialty Chemicals. A research-driven Exclusive Synthesis and CDMO company from India – with an established track record of demonstrated excellence in process development, process scale-up, process engineering, project management, and finally in consistent reliable custom manufacturing of chemicals for Crop Protection, Pharmaceutical, and other Fine / Specialty applications. INVENTYS advanced technologies ensure innovative, cost-effective, and safe processes.
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                Kimyagaran

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                  Norbuprenorphine

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                  78715-23-8
                  Buprenorphine
                  Established in 1995, Kimyagaran Emrooz Chemical Industries Co. is recognized as one of the major leading ...
                  Established in 1995, Kimyagaran Emrooz Chemical Industries Co. is recognized as one of the major leading production enterprises in the ethoxylation and propoxylation industry for manufacturing a wide variety of chemicals and pharmaceuticals in the Middle East. The company started out its journey by producing pharmaceutical polyethylene glycols (PEGs). It is currently the leading manufacturer of a wide variety of ethoxylated and propoxylated products that are consumed in 17 different industrial branches. The firm places a lot of emphasis on focuses a lot on research and development. The company currently boasts of over 3,000 customers.
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                  Kimyagaran

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                    3-O-Methyl Norbuprenorphine

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                    16614-59-8
                    Buprenorphine
                    Established in 1995, Kimyagaran Emrooz Chemical Industries Co. is recognized as one of the major leading ...
                    Established in 1995, Kimyagaran Emrooz Chemical Industries Co. is recognized as one of the major leading production enterprises in the ethoxylation and propoxylation industry for manufacturing a wide variety of chemicals and pharmaceuticals in the Middle East. The company started out its journey by producing pharmaceutical polyethylene glycols (PEGs). It is currently the leading manufacturer of a wide variety of ethoxylated and propoxylated products that are consumed in 17 different industrial branches. The firm places a lot of emphasis on focuses a lot on research and development. The company currently boasts of over 3,000 customers.
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                    Saintsun Pharma

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                      CYCLOPROPYL CARBINOL

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                      2516-33-8
                      Naltrexone
                      SAINTSUN PHARMA, we are engaging mainly in the manufacturing and distributing APIs, Pharmaceutical Interm...
                      SAINTSUN PHARMA, we are engaging mainly in the manufacturing and distributing APIs, Pharmaceutical Intermediates, Chemicals, Formulations, Medical supplies, etc... With a self-owned brand of "SAINTSUN PHARMA", after more than 12 years efforts, our products are successfully expanded to different continents like Asia, South America, Africa more than 35 countries and regions.
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                      Shree Ganesh Remedies

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                        Cyclopropane methylchloride

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                        5911-08-0
                        Naltrexone
                        Shree Ganesh Remedies is established Since 1995 with an aim to manufacture, supply and export best qualit...
                        Shree Ganesh Remedies is established Since 1995 with an aim to manufacture, supply and export best quality of Pharmaceutical-intermediates, Bulk drugs and Speciality Chemicals to cater the needs of pharmaceutical companies and drug companies for research and product development purpose
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                        Shree Ganesh Remedies

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                          Cyclopropane methylchloride

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                          5911-08-0
                          Buprenorphine
                          Shree Ganesh Remedies is established Since 1995 with an aim to manufacture, supply and export best qualit...
                          Shree Ganesh Remedies is established Since 1995 with an aim to manufacture, supply and export best quality of Pharmaceutical-intermediates, Bulk drugs and Speciality Chemicals to cater the needs of pharmaceutical companies and drug companies for research and product development purpose
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                          Shree Ganesh Remedies

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                            Cyclopropane Carboxylic Acid

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                            1759-53-1
                            Naltrexone
                            Shree Ganesh Remedies is established Since 1995 with an aim to manufacture, supply and export best qualit...
                            Shree Ganesh Remedies is established Since 1995 with an aim to manufacture, supply and export best quality of Pharmaceutical-intermediates, Bulk drugs and Speciality Chemicals to cater the needs of pharmaceutical companies and drug companies for research and product development purpose
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                            Shree Ganesh Remedies

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                              Cyclopropane Carbonyl Chloride

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                              4023-34-1
                              Naltrexone
                              Shree Ganesh Remedies is established Since 1995 with an aim to manufacture, supply and export best qualit...
                              Shree Ganesh Remedies is established Since 1995 with an aim to manufacture, supply and export best quality of Pharmaceutical-intermediates, Bulk drugs and Speciality Chemicals to cater the needs of pharmaceutical companies and drug companies for research and product development purpose
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                              Shree Ganesh Remedies

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                                Cyclopropane Carboxylic Acid

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                                1759-53-1
                                Buprenorphine
                                Shree Ganesh Remedies is established Since 1995 with an aim to manufacture, supply and export best qualit...
                                Shree Ganesh Remedies is established Since 1995 with an aim to manufacture, supply and export best quality of Pharmaceutical-intermediates, Bulk drugs and Speciality Chemicals to cater the needs of pharmaceutical companies and drug companies for research and product development purpose
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                                Shree Ganesh Remedies

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                                  Cyclopropane Carbonyl Chloride

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                                  4023-34-1
                                  Buprenorphine
                                  Shree Ganesh Remedies is established Since 1995 with an aim to manufacture, supply and export best qualit...
                                  Shree Ganesh Remedies is established Since 1995 with an aim to manufacture, supply and export best quality of Pharmaceutical-intermediates, Bulk drugs and Speciality Chemicals to cater the needs of pharmaceutical companies and drug companies for research and product development purpose
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                                  euroapi-2024-05-06

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                                  Minakem offers CDMO services for API & HPAPI, generics, regulatory expertise, track record performance & FDA & GMP certifications.

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