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Chemistry

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Also known as: 4-methyl-2-pentanone, 4-methylpentan-2-one, 108-10-1, Isopropylacetone, Isobutyl methyl ketone, Mibk
Molecular Formula
C6H12O
Molecular Weight
100.16  g/mol
InChI Key
NTIZESTWPVYFNL-UHFFFAOYSA-N
FDA UNII
U5T7B88CNP

Methyl isobutyl ketone
methyl isobutyl ketone is a natural product found in Aloe africana, Zingiber mioga, and other organisms with data available.
1 2D Structure

Methyl isobutyl ketone

2 Identification
2.1 Computed Descriptors
2.1.1 IUPAC Name
4-methylpentan-2-one
2.1.2 InChI
InChI=1S/C6H12O/c1-5(2)4-6(3)7/h5H,4H2,1-3H3
2.1.3 InChI Key
NTIZESTWPVYFNL-UHFFFAOYSA-N
2.1.4 Canonical SMILES
CC(C)CC(=O)C
2.2 Other Identifiers
2.2.1 UNII
U5T7B88CNP
2.3 Synonyms
2.3.1 MeSH Synonyms

1. 4-methyl-2-pentanone

2. Isobutyl Methyl Ketone

3. Isopropylacetone

2.3.2 Depositor-Supplied Synonyms

1. 4-methyl-2-pentanone

2. 4-methylpentan-2-one

3. 108-10-1

4. Isopropylacetone

5. Isobutyl Methyl Ketone

6. Mibk

7. 2-pentanone, 4-methyl-

8. Hexone

9. 2-methyl-4-pentanone

10. 4-methyl-2-oxopentane

11. Methylisobutylketon

12. Isohexanone

13. Hexon

14. Shell Mibk

15. Metilisobutilchetone

16. Metyloizobutyloketon

17. 2-methylpropyl Methyl Ketone

18. Isobutyl-methylketon

19. Methyl-isobutyl-cetone

20. 4-methyl-2-pentanon

21. 4-metilpentan-2-one

22. Isopropyl Acetone

23. Ketone, Isobutyl Methyl

24. 4-methyl-pentan-2-on

25. 4-methyl-pentan-2-one

26. Rcra Waste Number U161

27. Fema No. 2731

28. Nsc 5712

29. Methyl Isobutylketone

30. Methyl Iso-butyl Ketone

31. 2-methyl-4-pentanal

32. Methyl I-butyl Ketone

33. Ethyl Iso-butyl Ketone

34. Mfcd00008938

35. U5t7b88cnp

36. Methyl Isobutyl Ketone [nf]

37. Chebi:82344

38. Nsc-5712

39. Hexon [czech]

40. Methyl Isobutyl Ketone (nf)

41. Mik

42. Methylisobutyl Ketone

43. 4-methyl-2-pentanone, >=99%

44. Caswell No. 574aa

45. Fema Number 2731

46. Methylisobutylketone

47. Isobutyl-methylketon [czech]

48. Metyloizobutyloketon [polish]

49. Isobutylmethyl Ketone

50. Metilisobutilchetone [italian]

51. 4-methyl-2-pentanon [czech]

52. Ccris 2052

53. Hsdb 148

54. Methyl-isobutyl-cetone [french]

55. 4-metilpentan-2-one [italian]

56. 4-methyl-2-pentanone (natural)

57. 2-pentanone,4-methyl-

58. Methylisobutylketon [dutch, German]

59. Einecs 203-550-1

60. Un1245

61. Rcra Waste No. U161

62. Unii-u5t7b88cnp

63. Epa Pesticide Chemical Code 044105

64. Brn 0605399

65. 4-methyl-pentan-2-on [dutch, German]

66. Ai3-01229

67. Methylisobutyketone

68. Isobutylmethylketone

69. Methylisobutlyketone

70. I-bucome

71. Methylisobutyl Keton

72. Methylisobutyl-keton

73. Methylpentan-2-one

74. Iso-butylmethylketone

75. Methyl-isobutylketone

76. 4-methyl-2pentanone

77. Methy Isobutyl Ketone

78. Methyl Isobutyl Keton

79. Methyl Iso-butylketone

80. Methyl-iso-butylketone

81. Methyl-isobutyl Ketone

82. 4-methylpentane-2-one

83. Iso-c4h9coch3

84. Methyl-2-pentanon,4-

85. 4-methyl- 2-pentanone

86. Mibk [inci]

87. Dsstox_cid_1889

88. Ec 203-550-1

89. Dsstox_rid_76387

90. Dsstox_gsid_21889

91. Schembl15458

92. Isopropylacetone [mi]

93. 4-01-00-03305 (beilstein Handbook Reference)

94. 4-methyl-2-pentanone(mibk)

95. Chembl285323

96. Dtxsid5021889

97. Schembl13341539

98. Nsc5712

99. Methyl Isobutyl Ketone, Acs Grade

100. Amy11098

101. Zinc1482107

102. 4-methyl-2-pentanone, Hplc Grade

103. Methylisobutylketon(dutch, German)

104. Tox21_201108

105. Wln: 1y1 & 1v1

106. 4-methyl-2-pentanone [fcc]

107. Lmfa12000033

108. Methylisobutylketone [usp-rs]

109. Methyl Isobutyl Ketone [hsdb]

110. Methyl Isobutyl Ketone [iarc]

111. 4-methyl-2-pentanone [fhfi]

112. Akos000118793

113. 4-methyl-2-pentanone, Ar, >=99%

114. 4-methyl-2-pentanone, Lr, >=99%

115. Methyl Isobutyl Ketone [mart.]

116. Un 1245

117. 4-methyl-2-pentanone, >=99%, Fcc

118. Methyl Isobutyl Ketone [usp-rs]

119. Ncgc00091475-01

120. Ncgc00091475-02

121. Ncgc00258660-01

122. 4-methyl-pentan-2-on(dutch, German)

123. Bp-13453

124. Cas-108-10-1

125. Methyl Isobutyl Ketone Reagent Grade Acs

126. 4-methyl-2-pentanone, Analytical Standard

127. Ft-0628744

128. M0389

129. 4-methyl-2-pentanone, Technical Grade, 95%

130. 4-methyl-2-pentanone, For Hplc, >=99.5%

131. C19263

132. D04989

133. 4-methyl-2-pentanone, Acs Reagent, >=98.5%

134. A801806

135. Q418104

136. 4-methyl-2-pentanone, Saj First Grade, >=99.0%

137. J-515799

138. Methyl Isobutyl Ketone, P.a., Acs Reagent, 98.5%

139. Q-200495

140. 2-pentanone,4-methyl Methyl,isobutyl,ketone

141. 4-methyl-2-pentanone, Jis Special Grade, >=99.5%

142. Methyl Isobutyl Ketone [un1245] [flammable Liquid]

143. F1908-0087

144. 4-methyl-2-pentanone 1000 Microg/ml In N,n-dimethylformamide

145. 4-methyl-2-pentanone, Puriss. P.a., Acs Reagent, >=99.0% (gc)

146. 4-methyl-2-pentanone, Puriss., Acs Reagent, Reag. Ph. Eur., 99.0%

147. 4-methyl-2-pentanone, Suitable For Atomic Absorption Spectrometry, >=99.5%

148. Alfa-[(phenylmethoxy)carbonyl]oxy-1-piperidineaceticacidmethylester

149. Methyl Isobutyl Ketone, United States Pharmacopeia (usp) Reference Standard

150. Methyl Isobutyl Ketone, Pharmaceutical Secondary Standard; Certified Reference Material

2.4 Create Date
2005-03-26
3 Chemical and Physical Properties
Molecular Weight 100.16 g/mol
Molecular Formula C6H12O
XLogP31.3
Hydrogen Bond Donor Count0
Hydrogen Bond Acceptor Count1
Rotatable Bond Count2
Exact Mass100.088815002 g/mol
Monoisotopic Mass100.088815002 g/mol
Topological Polar Surface Area17.1 Ų
Heavy Atom Count7
Formal Charge0
Complexity64.6
Isotope Atom Count0
Defined Atom Stereocenter Count0
Undefined Atom Stereocenter Count0
Defined Bond Stereocenter Count0
Undefined Bond Stereocenter Count0
Covalently Bonded Unit Count1
4 Pharmacology and Biochemistry
4.1 Absorption, Distribution and Excretion

Methyl isobutyl ketone (MIBK) is a solvent used in numerous products and processes and may be present in the air of the workplace as a vapor. The American Conference of Governmental Industrial Hygienists (ACGIH) threshold limit value-time-weighted average (TLV-TWA) and TLV-short term exposure limit (TLV-STEL) for MIBK are 50 and 75 ppm, respectively. These workplace air concentration limits were set to protect workers from irritation, neurasthenic symptoms and possible adverse effects to their livers and kidneys. A recent revision of the ACGIH limit value has been proposed, to reduce the current TLV-TWA to 30 ppm. This article predicts the kinetics and accumulation of MIBK in humans exposed repeatedly in various exposure scenarios (8, 12, and 24 hr/day for 7 days) to the current ACGIH TLV-TWA of 50 ppm. The kinetic parameters of the model were derived from published human time-course blood MIBK data from a single 2 hr inhalation exposure to 48.9 ppm MIBK. The model correctly simulated single exposure experimental data with a rapid rise in blood concentration to 1.06 ug/mL within 1 hr and approached >or=99% steady-state blood level in 4 hr of exposure. MIBK was predicted to be rapidly eliminated from blood after terminating the exposure, reaching 0.53 ug/mL and 0.13 ug/mL within 0.5 and 2 hr post-exposure, respectively. Within 4h after the termination of exposure, blood concentration would be expected to <1% of the steady-state concentration. On the basis of these results, it is concluded that accumulation of MIBK in workers due to repeated inhalation exposure is not likely to occur at the current TLV-TWA concentration of 50 ppm.

PMID:18789368 Saghir SA, Rick DL; Regul Toxicol Pharmacol 52 (2): 180-8 (2008)


Methyl isobutyl ketone /was reported/ in human maternal blood samples collected immediately after delivery, indicating the potential for the compound to enter the umbilical cord and cross the placenta.

IARC. Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Humans. Geneva: World Health Organization, International Agency for Research on Cancer, 1972-PRESENT. (Multivolume work). Available at: https://monographs.iarc.fr/ENG/Classification/index.php, p. V101 312-3 (2013)


Methyl isobutyl ketone was detected in the brain, liver, lung, vitreous fluid, kidney, and blood in two workers who died after exposure to several organic solvents during spray painting. One died from a fall and the other died of cerebral edema 9 hours later. Tissue concentrations (mg/100 g) were reported to be: case 1 - brain, 0.25; liver, 0.49; lung, 0.43; vitreous fluid, 0.52; kidney, 0.24; and femoral blood, 0.14; and case 2 - brain, 0.06; liver, 0.22; lung, 0.11; vitreous fluid, 0.02; kidney, 0.08; and heart blood, 0.04.

IARC. Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Humans. Geneva: World Health Organization, International Agency for Research on Cancer, 1972-PRESENT. (Multivolume work). Available at: https://monographs.iarc.fr/ENG/Classification/index.php, p. V101 312 (2013)


Human volunteers (98 men and women) were exposed to 100 ppm (410 mg/cu m) methyl isobutyl ketone for 4 hours in an environmental chamber. Steady-state blood concentrations of methyl isobutyl ketone were attained after 2 hours of exposure. Blood and breath samples collected 90 minutes after exposure indicated that most of the absorbed compound had been eliminated from the body.

IARC. Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Humans. Geneva: World Health Organization, International Agency for Research on Cancer, 1972-PRESENT. (Multivolume work). Available at: https://monographs.iarc.fr/ENG/Classification/index.php, p. V101 312 (2013)


For more Absorption, Distribution and Excretion (Complete) data for Methyl isobutyl ketone (11 total), please visit the HSDB record page.


4.2 Metabolism/Metabolites

Methyl isobutyl ketone (MIBK) has recently been shown to potentiate the cholestasis induced by manganese-bilirubin (Mn-BR) or manganese (Mn) in rats. In this study, we investigated the effect of 4-methyl-2-pentanol (4MPOL) and 4-hydroxymethyl isobutyl ketone (4-OHMIBK), two major metabolites of MIBK, on these models of cholestasis. Dosages varying from 1.88 to 15 mmol/kg 4MPOL or 4-OHMIBK were administered once, 18 hr prior to the administration of a cholestatic Mn-BR combination. The cholestatic effect of the manganese-bilirubin combination was enhanced with dosages of 4MPOL of 3.75 mmol/kg and larger. On the other hand, dosages smaller than 15 mmol/kg of 4-OHMIBK did not potentiate the Mn-BR cholestasis. Daily pretreatment for 3 days resulted in an increased response to the cholestatic challenges of either Mn-BR or Mn alone. 4MPOL administered repetitively was a better potentiator than 4-OHMIBK with the Mn-BR model of cholestasis. However, with Mn alone, 4-OHMIBK proved to be more effective. 4MPOL and 4-OHMIBK per se were devoid of cholestatic properties, since the bile flow measured prior to the cholestatic challenge was not decreased and in some cases was significantly greater than that of vehicle-pretreated animals. These results show that MIBK metabolites can potentiate the cholestatic form of hepatotoxicity. /4-methyl-2-pentanol and 4-hydroxymethyl isobutyl ketone (metabolites)/

PMID:3353988 Vezina M, Plaa GL; Toxicol Appl Pharmacol 92 (3): 419-27 (1988)


The absorption and metabolism of MIBK was studied in male Sprague-Dawley rats orally administered a single dose of 5 mmol/kg body weight of MIBK in corn oil, equivalent to 501 mg/kg body weight, by gavage. MIBK was rapidly absorbed into the systemic circulation following oral exposure, with a mean maximum plasma concentration (Cmax) of 0.644 mmol/L occurring at 0.25 hours [(time to maximum plasma concentration (tmax)] post-administration. MIBK was detected at very low levels (0.006 mmol/L) at 9 hours post-administration. The plasma levels of methyl isobutyl carbinol (MIBC) were very low (<0.012 mmol/L) all over the study. The major material in the blood was 4-hydroxymethyl-4-methyl-2-pentanone (referred to as HMP based on the chemical name) [i.e., diacetone alcohol (DAA], with a Cmax of 2.03 mmol/L at 9 hours and remained detectable at 12 hours post-dosing. Neither MIBK nor MIBC were detectable in 12-hour samples. No compounds other than HMP and MIBK were detected in the blood. The 12-hour area under the plasma concentration time curve (AUC0-12 h) for MIBK, MIBC and HMP were 0.089, 3.558 and 17, 436 mmol/L/hour, respectively. HMP and MIBK represented 79% and 20% of the total AUC, respectively. The plasma elimination half-life (t1/2) of MIBK and HMP were 2.529 and 4.831 hours, respectively. Based on the results of this study, MIBK is rapidly absorbed into the blood in rats following oral exposure and is rapidly and extensively metabolized to HMP (the major metabolite in blood after 3 hours).

European Chemicals Agency (ECHA); Registered Substances, 4-Methylpentan-2-one (CAS Number: 108-10-1) (EC Number: 203-550-1) (Last modified: January 22, 2018). Available from, as of February 21, 2018: https://echa.europa.eu/


Methyl isobutyl carbinol (MIBC) is an oxygenated solvent that is metabolized to methylisobutyl ketone (MIBK) and then to 4-hydroxymethyl-4-methyl-2-pentanone (HMP). Plasma levels of MIBC, MIBK and HMP were determined up to 12 hr after a single oral 5 mmol/kg dose of MIBC or MIBK to male rats. The major material in the plasma in both cases was HMP, with similar areas-under-the-curve (AUC) and C(max) at 9 hr after dosing. MIBK plasma levels and AUC were also comparable after MIBK or MIBC administration. MIBC AUC was only about 6% of the total material in the blood after MIBC, and insignificant after MIBK administration. No other metabolites were detected in the plasma under the analytical conditions used. The extent of metabolism of MIBC to MIBK, by comparing combined AUCs for MIBK and HMP, was at least 73%. ...

PMID:12505273 Gingell R et al; Toxicol Lett 136 (3): 199-204 (2003)


The metabolic fate of methyl n-butyl ketone (MnBK) and its isomer methyl isobutyl ketone (MiBK) was studied in mice. The concentrations of both ketones and their metabolites in blood and brain were measured at different time intervals after their administration. The principal metabolites of ... MiBK were 4-methyl-2-pentanol (4-MPOL) and 4-hydroxy-4 methyl-2-pentanone (HMP). .... The administration of 4-methyl-2-pentanol resulted in the appearance of MiBK and HMP. The administration of HMP did not result in the appearance of MiBK or 4-MPOL. ....

PMID:8284793 Granvil CP et al; Toxicol Lett 70 (3): 263-7 (1994)


For more Metabolism/Metabolites (Complete) data for Methyl isobutyl ketone (7 total), please visit the HSDB record page.


4.3 Biological Half-Life

Blood: initial fast phase = 12 minutes, then slow phase = 1 hour; [TDR, p. 886]

TDR - Ryan RP, Terry CE, Leffingwell SS (eds). Toxicology Desk Reference: The Toxic Exposure and Medical Monitoring Index, 5th Ed. Washington DC: Taylor & Francis, 1999., p. 886


The absorption and metabolism of MIBK was studied in male Sprague-Dawley rats orally administered a single dose of 5 mmol/kg body weight of MIBK in corn oil, equivalent to 501 mg/kg body weight, by gavage. ... The plasma elimination half-life (t1/2) of MIBK ... was 2.529 hours ... .

European Chemicals Agency (ECHA); Registered Substances, 4-Methylpentan-2-one (CAS Number: 108-10-1) (EC Number: 203-550-1) (Last modified: January 22, 2018). Available from, as of February 21, 2018: https://echa.europa.eu/


In Guinea pigs serum half-lives and clearance times for methyl isobutyl ketone was 66 min and 6 hr respectively.

PMID:941151 Divincenzo GD et al; Toxicol Appl Pharmacol 36 (3): 511-22 (1976)


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01-Jan-2022
27-Jun-2025
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Looking for 108-10-1 / Methyl isobutyl ketone API manufacturers, exporters & distributors?

Methyl isobutyl ketone manufacturers, exporters & distributors 1

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PharmaCompass offers a list of Methyl isobutyl ketone API manufacturers, exporters & distributors, which can be sorted by GMP, USDMF, JDMF, KDMF, CEP (COS), WC, Price,and more, enabling you to easily find the right Methyl isobutyl ketone manufacturer or Methyl isobutyl ketone supplier for your needs.

Send us enquiries for free, and we will assist you in establishing a direct connection with your preferred Methyl isobutyl ketone manufacturer or Methyl isobutyl ketone supplier.

PharmaCompass also assists you with knowing the Methyl isobutyl ketone API Price utilized in the formulation of products. Methyl isobutyl ketone API Price is not always fixed or binding as the Methyl isobutyl ketone Price is obtained through a variety of data sources. The Methyl isobutyl ketone Price can also vary due to multiple factors, including market conditions, regulatory modifications, or negotiated pricing deals.

API | Excipient name

Methyl isobutyl ketone

Synonyms

4-methyl-2-pentanone, 4-methylpentan-2-one, 108-10-1, Isopropylacetone, Isobutyl methyl ketone, Mibk

Cas Number

108-10-1

Unique Ingredient Identifier (UNII)

U5T7B88CNP

About Methyl isobutyl ketone

methyl isobutyl ketone is a natural product found in Aloe africana, Zingiber mioga, and other organisms with data available.

Methyl isobutyl ketone Manufacturers

A Methyl isobutyl ketone manufacturer is defined as any person or entity involved in the manufacture, preparation, processing, compounding or propagation of Methyl isobutyl ketone, including repackagers and relabelers. The FDA regulates Methyl isobutyl ketone manufacturers to ensure that their products comply with relevant laws and regulations and are safe and effective to use. Methyl isobutyl ketone API Manufacturers are required to adhere to Good Manufacturing Practices (GMP) to ensure that their products are consistently manufactured to meet established quality criteria.

click here to find a list of Methyl isobutyl ketone manufacturers with USDMF, JDMF, KDMF, CEP, GMP, COA and API Price related information on PhamaCompass.

Methyl isobutyl ketone Suppliers

A Methyl isobutyl ketone supplier is an individual or a company that provides Methyl isobutyl ketone active pharmaceutical ingredient (API) or Methyl isobutyl ketone finished formulations upon request. The Methyl isobutyl ketone suppliers may include Methyl isobutyl ketone API manufacturers, exporters, distributors and traders.

click here to find a list of Methyl isobutyl ketone suppliers with USDMF, JDMF, KDMF, CEP, GMP, COA and API Price related information on PharmaCompass.

Methyl isobutyl ketone GMP

Methyl isobutyl ketone Active pharmaceutical ingredient (API) is produced in GMP-certified manufacturing facility.

GMP stands for Good Manufacturing Practices, which is a system used in the pharmaceutical industry to make sure that goods are regularly produced and monitored in accordance with quality standards. The FDA’s current Good Manufacturing Practices requirements are referred to as cGMP or current GMP which indicates that the company follows the most recent GMP specifications. The World Health Organization (WHO) has its own set of GMP guidelines, called the WHO GMP. Different countries can also set their own guidelines for GMP like China (Chinese GMP) or the EU (EU GMP).

PharmaCompass offers a list of Methyl isobutyl ketone GMP manufacturers, exporters & distributors, which can be sorted by USDMF, JDMF, KDMF, CEP (COS), WC, API price, and more, enabling you to easily find the right Methyl isobutyl ketone GMP manufacturer or Methyl isobutyl ketone GMP API supplier for your needs.

Methyl isobutyl ketone CoA

A Methyl isobutyl ketone CoA (Certificate of Analysis) is a formal document that attests to Methyl isobutyl ketone's compliance with Methyl isobutyl ketone specifications and serves as a tool for batch-level quality control.

Methyl isobutyl ketone CoA mostly includes findings from lab analyses of a specific batch. For each Methyl isobutyl ketone CoA document that a company creates, the USFDA specifies specific requirements, such as supplier information, material identification, transportation data, evidence of conformity and signature data.

Methyl isobutyl ketone may be tested according to a variety of international standards, such as European Pharmacopoeia (Methyl isobutyl ketone EP), Methyl isobutyl ketone JP (Japanese Pharmacopeia) and the US Pharmacopoeia (Methyl isobutyl ketone USP).

Inform the supplier about your product requirements, specifying if you need a product with particular monograph like EP (Ph. Eur.), USP, JP, BP, or any other quality. In addition, clarify whether you need hydrochloride (HCl), anhydricum, base, micronisatum or a specific level of purity. To find reputable suppliers, utilize the filters and select those certified by GMP, FDA, or any other certification as per your requirement.
For your convenience, we have listed synonyms and CAS numbers to help you find the best supplier. The use of synonyms and CAS numbers can be helpful in identifying potential suppliers, but it is crucial to note that they might not always indicate the exact same product. It is important to confirm the product details with the supplier before making a purchase to ensure that it meets your requirements.
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