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Chemistry

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Also known as: 75-75-2, Methylsulfonic acid, Methanesulphonic acid, Mesylate, Mesylic acid, Kyselina methansulfonova
Molecular Formula
CH4O3S
Molecular Weight
96.11  g/mol
InChI Key
AFVFQIVMOAPDHO-UHFFFAOYSA-N
FDA UNII
12EH9M7279

Methanesulphonic acid
1 2D Structure

Methanesulphonic acid

2 Identification
2.1 Computed Descriptors
2.1.1 IUPAC Name
methanesulfonic acid
2.1.2 InChI
InChI=1S/CH4O3S/c1-5(2,3)4/h1H3,(H,2,3,4)
2.1.3 InChI Key
AFVFQIVMOAPDHO-UHFFFAOYSA-N
2.1.4 Canonical SMILES
CS(=O)(=O)O
2.2 Other Identifiers
2.2.1 UNII
12EH9M7279
2.3 Synonyms
2.3.1 MeSH Synonyms

1. Barium Methanesulfonate

2. Bms-480188

3. Methanesulfonate

4. Methanesulfonic Acid, Ammonia Salt

5. Methanesulfonic Acid, Chromium (2+) Salt

6. Methanesulfonic Acid, Chromium (3+) Salt

7. Methanesulfonic Acid, Cobalt (2+) Salt

8. Methanesulfonic Acid, Copper (2+) Salt

9. Methanesulfonic Acid, Iron (2+) Salt

10. Methanesulfonic Acid, Iron (3+)salt

11. Methanesulfonic Acid, Nickel (2+) Salt

12. Methanesulfonic Acid, Potassium Salt

13. Methanesulfonic Acid, Silver (1+) Salt

14. Methanesulfonic Acid, Sodium Salt

15. Methylsulfonate

16. Potassium Mesylate

17. Potassium Methanesulfonate

2.3.2 Depositor-Supplied Synonyms

1. 75-75-2

2. Methylsulfonic Acid

3. Methanesulphonic Acid

4. Mesylate

5. Mesylic Acid

6. Kyselina Methansulfonova

7. Sulfomethane

8. Methansulfonsaeure

9. Nsc 3718

10. Ch3so3h

11. Mfcd00007518

12. Chebi:27376

13. 22515-76-0

14. Msa

15. Nsc-3718

16. 12eh9m7279

17. Ammoniummethanesulfonate

18. Ccris 2783

19. Kyselina Methansulfonova [czech]

20. Hsdb 5004

21. Einecs 200-898-6

22. Brn 1446024

23. Methane Sulfonic Acid

24. Ai3-28532

25. Unii-12eh9m7279

26. Metanesulfonic Acid

27. Methansulfonic Acid

28. Msoh

29. Methansulphonic Acid

30. Methylsulphonic Acid

31. 03s

32. Methyl Sulfonic Acid

33. Methyl-sulfonic Acid

34. Methane-sulfonic Acid

35. Meso3h

36. Methane Sulphonic Acid

37. Methanesulphonic-acid-

38. Lactic Acid(dl)

39. Ammonium Methanesulphonate

40. Ch3so2oh

41. H3cso3h

42. Dsstox_cid_6422

43. Wln: Wsq1

44. Ec 200-898-6

45. Dsstox_rid_78109

46. Methane Sulfonic Acid 99%

47. Methanesulfonic Acid Solution

48. Dsstox_gsid_26422

49. 4-04-00-00010 (beilstein Handbook Reference)

50. Methanesulfonic Acid, 99.5%

51. Methanesulfonic Acid, Anhydrous

52. Chembl3039600

53. Dl-malicacidmonosodiumsalt

54. Dtxsid4026422

55. Methanesulfonic Acid [ii]

56. Methanesulfonic Acid [mi]

57. Methanesulfonic Acid, Hplc Grade

58. Nsc3718

59. Methanesulfonic Acid, >=99.0%

60. Methanesulfonic Acid [hsdb]

61. Tox21_201073

62. Stl264182

63. Methane Sulfonic Acid, 70% Solution

64. Akos009146947

65. At25153

66. J1.465f

67. Cas-75-75-2

68. Ncgc00248914-01

69. Ncgc00258626-01

70. Bp-12823

71. Db-075013

72. Ft-0628287

73. M0093

74. M2059

75. Methanesulfonic Acid, >=99.0%, Reagentplus(r)

76. Methanesulfonic Acid, For Hplc, >=99.5% (t)

77. A934985

78. Methanesulfonic Acid Solution, 70 Wt. % In H2o

79. Q414168

80. J-521696

81. Methanesulfonic Acid, Vetec(tm) Reagent Grade, 98%

82. F1908-0093

83. Z940713430

84. Methanesulfonic Acid Solution, 4 M (with 0.2% (w/v) Tryptamine)

85. Methanesulfonic Acid Concentrate, 0.1 M Ch3so3h In Water (0.1n), Eluent Concentrate For Ic

86. Methanesulfonic Acid, Pharmagrade, Manufactured Under Appropriate Gmp Controls For Pharma Or Biopharmaceutical Production

2.4 Create Date
2004-09-16
3 Chemical and Physical Properties
Molecular Weight 96.11 g/mol
Molecular Formula CH4O3S
XLogP3-0.9
Hydrogen Bond Donor Count1
Hydrogen Bond Acceptor Count3
Rotatable Bond Count0
Exact Mass95.98811516 g/mol
Monoisotopic Mass95.98811516 g/mol
Topological Polar Surface Area62.8 Ų
Heavy Atom Count5
Formal Charge0
Complexity92.6
Isotope Atom Count0
Defined Atom Stereocenter Count0
Undefined Atom Stereocenter Count0
Defined Bond Stereocenter Count0
Undefined Bond Stereocenter Count0
Covalently Bonded Unit Count1
4 Pharmacology and Biochemistry
4.1 Absorption, Distribution and Excretion

Not absorbed /through skin/; excreted /unchanged/ in rats after 1 g/kg administered sc. /From table/

Patty, F. (ed.). Industrial Hygiene and Toxicology: Volume II: Toxicology. 2nd ed. New York: Interscience Publishers, 1963., p. 1844


4.2 Metabolism/Metabolites

Marinosulfonomonas methylotropha strain TR3 is a marine methylotroph that uses methanesulfonic acid (MSA) as a sole carbon and energy source. The genes from M. methylotropha strain TR3 encoding methanesulfonate monooxygenase, the enzyme responsible for the initial oxidation of MSA to formaldehyde and sulfite, were cloned and sequenced. They were located on two gene clusters on the chromosome of this bacterium. A 5.0-kbp HindIII fragment contained msmA, msmB, and msmC, encoding the large and small subunits of the hydroxylase component and the ferredoxin component, respectively, of the methanesulfonate monooxygenase, while a 6.5-kbp HindIII fragment contained duplicate copies of msmA and msmB, as well as msmD, encoding the reductase component of methanesulfonate. Both sets of msmA and msmB genes were virtually identical, and the derived msmA and msmB sequences of M. methylotropha strain TR3, compared with the corresponding hydroxylase from the terrestrial MSA utilizer Methylosulfonomonas methylovora strain M2 were found to be 82 and 69% identical. The msmA gene was investigated as a functional gene probe for detection of MSA-utilizing bacteria. PCR primers spanning a region of msmA which encoded a unique Rieske [2Fe-2S] binding region were designed. These primers were used to amplify the corresponding msmA genes from newly isolated Hyphomicrobium, Methylobacterium, and Pedomicrobium species that utilized MSA, from MSA enrichment cultures, and from DNA samples extracted directly from the environment. The high degree of identity of these msmA gene fragments, compared to msmA sequences from extant MSA utilizers, indicated the effectiveness of these PCR primers in molecular microbial ecology.

Baxter, NJ et al; Appl Environ Microbiol 68 (1) 289-96 (2002) https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?cmd=Retrieve&db=pubmed&dopt=Abstract&list_uids=11772638


4.3 Mechanism of Action

Methylating agents are potent carcinogens that are mutagenic and cytotoxic towards bacteria and mammalian cells. Their effects can be ascribed to an ability to modify DNA covalently. Pioneering studies of the chemical reactivity of methylating agents towards DNA components and their effectiveness as animal carcinogens identified O(6)-methylguanine (O(6)meG) as a potentially important DNA lesion. Subsequent analysis of the effects of methylating carcinogens in bacteria and cultured mammalian cells - including the discovery of the inducible adaptive response to alkylating agents in Escherichia coli - have defined the contributions of O(6)meG and other methylated DNA bases to the biological effects of these chemicals. More recently, the role of O(6)meG in killing mammalian cells has been revealed by the lethal interaction between persistent DNA O(6)meG and the mismatch repair pathway. Here, ...the results which led to the identification of the biological consequences of persistent DNA O(6)meG are reviewed. ... The possible consequences for a human cell of chronic exposure to low levels of a methylating agent /are considered/. Such exposure may increase the probability that the cell's mismatch repair pathway becomes inactive. Loss of mismatch repair predisposes the cell to mutation induction, not only through uncorrected replication errors but also by methylating agents and other mutagens. /Alkylating agents/

Bignami M et al Mutat Res 462 (2-3): 71-82 (2000). Available from, as of November 20, 2009: https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?cmd=Retrieve&db=pubmed&dopt=Abstract&list_uids=10767619


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Methanesulphonic acid USP

Date of Issue : 2024-02-12

Valid Till : 2027-02-11

Written Confirmation Number : WC-0407

Address of the Firm : Sy. No. 205, 222 to 226, IDA Bonthapally, Bonthapally (Village), Gummadidala (Ma...

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Methanesulphonic acid

About the Company : Tenatra International was established as a proprietorship firm in 1999. It got off to a very good start, supporting clients in the United States, Mexico and Europe. As business opp...

Tenatra International was established as a proprietorship firm in 1999. It got off to a very good start, supporting clients in the United States, Mexico and Europe. As business opportunities grew, it was felt that the proprietorship firm had outlived its usefulness and that it needed a corporate structure. So, Tenatra Chemie Private Limited (TCPL) was incorporated in 2002. Since then, the company has come a long way, gaining valuable experience and knowledge in the fields of chemicals and pharmaceuticals in India.
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KING\\'S ROAD, QUARRY BAY,HONG KONG Hong Kong","customerAddress":"105, BAJAJ BHAVAN, NARIMAN POINT"}]
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Excipient Market Overview: Roquette, Seqens, Evonik make strategic moves; new guidelines deal with contamination
The pharmaceutical industry has long recognized the critical role excipients or inactive ingredients play in drug formulation and delivery. Excipients can comprise up to 90 percent of a medicine's total ingredients and serve crucial functions as binders, disintegrants, coatings, preservatives, colors, and flavorings. According to recent market research, the pharmaceutical excipients market was valued at US$ 9.27 billion in 2023. It is growing at a compound annual growth rate (CAGR) of 7.03 percent and is projected to reach US$ 18.48 billion by 2032. The main factors driving market growth is an increased demand for multifunctional excipients, coupled with the expanding use of generic medications. The development in the biologics sector and advancements in nanotechnology are also contributing significantly to market growth. Major excipient providers include BASF, Evonik, Merck KGaA owned MilliporeSigma, Gangwal Healthcare, Roquette Frères, DuPont, Croda International, Seqens, Boai NKY Pharmaceuticals, PMC Isochem, Minakem, Kewpie Corporation, Ashland Global, SPI Pharma, Pfanstiehl, Nanjing Well Pharmaceutical, ICE Pharma, Anhui Ribobay Pharmaceutical and Nippon Fine Chemical.  View Our Dashboard on Major Excipient Companies in 2024 (Free Excel Available) WHO, India’s CDSCO tighten regulations; new GMP guidelines implemented to curb contamination Last year, the World Health Organization (WHO) issued a health alert linking at least 300 child deaths in the Gambia, Uzbekistan, and Indonesia to the ingestion of contaminated cough syrups containing unacceptable levels of diethylene glycol (DEG) and ethylene glycol (EG). In response to the tragic events, the WHO released two draft appendices to its guideline on good manufacturing practices (GMPs) for excipients this year. Manufacturers are now required to use suitable risk assessment tools to identify and mitigate potential hazards.  Since India-made cough syrups had been linked to the deaths, India’s drug regulator — Central Drugs Standard Control Organization (CDSCO) — took steps to prevent contamination, and advised drugmakers to only use pharmaceutical-grade excipients from approved sources. Furthermore, the Indian Health Ministry proposed amendments to the Drugs and Cosmetics Rules, 1945 to include details of excipients on drug labels. While listing all excipients on every strip of medicine may be challenging, the ministry suggested mentioning those causing hypersensitivity on the label. Applicants now mandatorily need to submit evidence of stability and safety of excipients. These regulatory developments have significant implications for excipient manufacturers and pharmaceutical companies worldwide. Leading pharmaceutical excipient firms like Gangwal Healthcare, Sigachi Industries, and Nitika Pharmaceuticals are well-positioned to meet these heightened quality and safety standards, given their long-standing commitment to producing high-quality, compliant excipients.  View Our Dashboard on Major Excipient Companies in 2024 (Free Excel Available)   Roquette buys IFF’s pharma unit for US$ 2.85 bn; Evonik opens new spray-drying facility in Darmstadt In a significant industry move, France-based Roquette entered into an agreement to acquire IFF's pharma solutions business in a deal valued at US$ 2.85 billion. This acquisition is set to rebalance family-owned Roquette’s portfolio around health and nutrition. The deal is expected to accelerate Roquette’s growth and significantly strengthen its presence in the excipients market. Evonik has opened a new facility for drying aqueous dispersions of its Eudragit polymers at its site in Darmstadt, Germany. The facility will help Evonik meet increasing demand from drugmakers for its oral drug delivery solutions. The plant uses green energy solutions. The company has also partnered University of Mainz to commercialize a new class of polyethylene glycols (PEG) lipids for nucleic acid delivery. Evonik’s Health Care business has been growing its nucleic acid drug and vaccine delivery portfolio.  Germany’s Johannes Gutenberg University of Mainz was the first to develop randomized polyethylene glycols (rPEGs). This collaboration aims to expand Evonik’s toolbox of technologies for nucleic acid-based medicines, offering an improved immunogenicity profile for lipid nanoparticle carriers used in mRNA vaccines and therapeutics. Asahi Kasei made significant strides in addressing a pressing industry concern that emerged in 2018 when potentially carcinogenic nitrosamine impurities were detected in several pharmaceuticals. Guided by regional authorities, such as the European Medicines Agency and the US Food and Drug Administration, the pharmaceutical industry has been carrying out extensive assessments and research to identify the cause of these impurities. In response to this challenge, Asahi Kasei developed its Ceolus microcrystalline cellulose with extremely low nitrite levels. The Japanese company achieved nitrite concentrations of 0.1 micrograms per gram or less, which is equivalent to 0.1 parts per million (ppm). The company also started full commercial operation of its second manufacturing facility for Ceolus in Japan, enhancing supply capacity and stability. JRS Pharma and Gujarat Microwax opened a state-of-the-art cotton-based croscarmellose sodium plant in Mehsana, Gujarat (India). This facility aims to produce high-quality excipients that meet global standards, potentially reducing India's dependency on imports and boosting its presence in the global excipient market. The Indian excipient industry accounts for less than 1 percent of the global market share.  View Our Dashboard on Major Excipient Companies in 2024 (Free Excel Available)   Seqens to advance innovative polymer; biologics, personalized medicine create demand for specialized excipients Recent industry collaborations highlight the ongoing innovation in novel excipients. France’s Seqens, with over 20 years of polymer development experience, was chosen by Pleryon Therapeutics to advance its leading osteoarthritis candidate – an innovative GMP polymer. This collaboration leverages Seqens’ newly expanded and modernized cGMP plant in Aramon, France, demonstrating the industry’s commitment to investing in advanced manufacturing capabilities for novel excipients.  The rise of biologics and personalized medicine has created a demand for specialized excipients capable of stabilizing complex molecules and enabling targeted drug delivery. Roquette’s launch of Lycagel Flex, a hydroxypropyl pemix for nutraceutical and pharmaceutical softgel capsules, exemplifies this trend. Built on Roquette’s market-first Lycagel pea starch technology, this plant-based alternative to gelatin offers manufacturers the flexibility to customize formulations for a range of production and end-user needs. The innovative pea starch foundation also underscores the industry’s move towards sustainable bio-based excipients. The trend towards patient-centric drug development has also influenced excipient innovation. Excipients that can improve palatability, ease of swallowing, or enable novel dosage forms (such as orally disintegrating tablets) are in high demand. For example, IFF brought a super disintegrant Ac-Di-Sol, that supports faster disintegration and drug dissolution in oral disintegrating tablets, improving patient experience.  View Our Dashboard on Major Excipient Companies in 2024 (Free Excel Available)   Our view The heightened regulatory scrutiny on excipients due to product contamination incidents has created a high risk perception and uncertainty around the regulatory acceptance of novel excipients. That said, novel excipients are central to the development of new drug modalities and therapies. Going forward, sustainability will also become an increasingly important factor in excipient selection and development. As the industry innovates towards biologics, personalized therapies, and patient-centric formulations, the role of high-quality, multifunctional excipients will only grow more vital in ensuring drug stability, bioavailability, and patient compliance. Companies that can navigate the complex regulatory landscape, invest in R&D, and offer high-quality, multifunctional excipients will be well-positioned to succeed in this evolving market.   

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https://www.pharmacompass.com/radio-compass-blog/excipient-market-overview-roquette-seqens-evonik-make-strategic-moves-new-guidelines-deal-with-contamination

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12 Sep 2024

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Looking for 75-75-2 / Methanesulphonic acid API manufacturers, exporters & distributors?

Methanesulphonic acid manufacturers, exporters & distributors 1

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PharmaCompass offers a list of Methanesulphonic acid API manufacturers, exporters & distributors, which can be sorted by GMP, USDMF, JDMF, KDMF, CEP (COS), WC, Price,and more, enabling you to easily find the right Methanesulphonic acid manufacturer or Methanesulphonic acid supplier for your needs.

Send us enquiries for free, and we will assist you in establishing a direct connection with your preferred Methanesulphonic acid manufacturer or Methanesulphonic acid supplier.

PharmaCompass also assists you with knowing the Methanesulphonic acid API Price utilized in the formulation of products. Methanesulphonic acid API Price is not always fixed or binding as the Methanesulphonic acid Price is obtained through a variety of data sources. The Methanesulphonic acid Price can also vary due to multiple factors, including market conditions, regulatory modifications, or negotiated pricing deals.

API | Excipient name

Methanesulphonic acid

Synonyms

75-75-2, Methylsulfonic acid, Mesylate, Mesylic acid, Kyselina methansulfonova, Sulfomethane

Cas Number

75-75-2

Unique Ingredient Identifier (UNII)

12EH9M7279

Methanesulphonic acid Manufacturers

A Methanesulphonic acid manufacturer is defined as any person or entity involved in the manufacture, preparation, processing, compounding or propagation of Methanesulphonic acid, including repackagers and relabelers. The FDA regulates Methanesulphonic acid manufacturers to ensure that their products comply with relevant laws and regulations and are safe and effective to use. Methanesulphonic acid API Manufacturers are required to adhere to Good Manufacturing Practices (GMP) to ensure that their products are consistently manufactured to meet established quality criteria.

click here to find a list of Methanesulphonic acid manufacturers with USDMF, JDMF, KDMF, CEP, GMP, COA and API Price related information on PhamaCompass.

Methanesulphonic acid Suppliers

A Methanesulphonic acid supplier is an individual or a company that provides Methanesulphonic acid active pharmaceutical ingredient (API) or Methanesulphonic acid finished formulations upon request. The Methanesulphonic acid suppliers may include Methanesulphonic acid API manufacturers, exporters, distributors and traders.

click here to find a list of Methanesulphonic acid suppliers with USDMF, JDMF, KDMF, CEP, GMP, COA and API Price related information on PharmaCompass.

Methanesulphonic acid USDMF

A Methanesulphonic acid DMF (Drug Master File) is a document detailing the whole manufacturing process of Methanesulphonic acid active pharmaceutical ingredient (API) in detail. Different forms of Methanesulphonic acid DMFs exist exist since differing nations have different regulations, such as Methanesulphonic acid USDMF, ASMF (EDMF), JDMF, CDMF, etc.

A Methanesulphonic acid DMF submitted to regulatory agencies in the US is known as a USDMF. Methanesulphonic acid USDMF includes data on Methanesulphonic acid's chemical properties, information on the facilities and procedures used, and details about packaging and storage. The Methanesulphonic acid USDMF is kept confidential to protect the manufacturer’s intellectual property.

click here to find a list of Methanesulphonic acid suppliers with USDMF on PharmaCompass.

Methanesulphonic acid WC

A Methanesulphonic acid written confirmation (Methanesulphonic acid WC) is an official document issued by a regulatory agency to a Methanesulphonic acid manufacturer, verifying that the manufacturing facility of a Methanesulphonic acid active pharmaceutical ingredient (API) adheres to the Good Manufacturing Practices (GMP) regulations of the importing country. When exporting Methanesulphonic acid APIs or Methanesulphonic acid finished pharmaceutical products to another nation, regulatory agencies frequently require a Methanesulphonic acid WC (written confirmation) as part of the regulatory process.

click here to find a list of Methanesulphonic acid suppliers with Written Confirmation (WC) on PharmaCompass.

Methanesulphonic acid GMP

Methanesulphonic acid Active pharmaceutical ingredient (API) is produced in GMP-certified manufacturing facility.

GMP stands for Good Manufacturing Practices, which is a system used in the pharmaceutical industry to make sure that goods are regularly produced and monitored in accordance with quality standards. The FDA’s current Good Manufacturing Practices requirements are referred to as cGMP or current GMP which indicates that the company follows the most recent GMP specifications. The World Health Organization (WHO) has its own set of GMP guidelines, called the WHO GMP. Different countries can also set their own guidelines for GMP like China (Chinese GMP) or the EU (EU GMP).

PharmaCompass offers a list of Methanesulphonic acid GMP manufacturers, exporters & distributors, which can be sorted by USDMF, JDMF, KDMF, CEP (COS), WC, API price, and more, enabling you to easily find the right Methanesulphonic acid GMP manufacturer or Methanesulphonic acid GMP API supplier for your needs.

Methanesulphonic acid CoA

A Methanesulphonic acid CoA (Certificate of Analysis) is a formal document that attests to Methanesulphonic acid's compliance with Methanesulphonic acid specifications and serves as a tool for batch-level quality control.

Methanesulphonic acid CoA mostly includes findings from lab analyses of a specific batch. For each Methanesulphonic acid CoA document that a company creates, the USFDA specifies specific requirements, such as supplier information, material identification, transportation data, evidence of conformity and signature data.

Methanesulphonic acid may be tested according to a variety of international standards, such as European Pharmacopoeia (Methanesulphonic acid EP), Methanesulphonic acid JP (Japanese Pharmacopeia) and the US Pharmacopoeia (Methanesulphonic acid USP).

Inform the supplier about your product requirements, specifying if you need a product with particular monograph like EP (Ph. Eur.), USP, JP, BP, or any other quality. In addition, clarify whether you need hydrochloride (HCl), anhydricum, base, micronisatum or a specific level of purity. To find reputable suppliers, utilize the filters and select those certified by GMP, FDA, or any other certification as per your requirement.
For your convenience, we have listed synonyms and CAS numbers to help you find the best supplier. The use of synonyms and CAS numbers can be helpful in identifying potential suppliers, but it is crucial to note that they might not always indicate the exact same product. It is important to confirm the product details with the supplier before making a purchase to ensure that it meets your requirements.
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